Please use this identifier to cite or link to this item: http://dl.merc.ac.ir/handle/Hannan/52926
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dc.contributor.authorShard, Amit-
dc.contributor.authorKumar, Rajesh-
dc.contributor.authorSaima-
dc.contributor.authorSharma, Nidhi-
dc.contributor.authorSinha, A K-
dc.date2014-09-29T11:11:11Z-
dc.date2014-09-29T11:11:11Z-
dc.date.accessioned2015-01-06T12:52:08Z-
dc.date.available2015-01-06T12:52:08Z-
dc.date.issued2014-
dc.identifierRSC Advances, 2014, 4(63), 33399-33407-
dc.identifier.urihttp://hdl.handle.net/123456789/1415-
dc.descriptionA green methodology utilizing natural auxiliary like L-Arginine in conjunction with water and oxygen led to oxidative coupling of thiols into disulfides (S-S bond) whereas thiol-yne coupling (TYC) to access vinyl sulfides (C-S bond) was facilitated in nitrogen atmosphere. The tunable protocol offers several advantages like low catalyst loading, high yields, clean reaction, no over-oxidation of S-S bond besides being metal/base/waste-free. The synthesis of ubiquitous cystine and GSSG in the same catalytic system is an added advantage and the catalytic system has been recycled up to seven times.-
dc.format348659 bytes-
dc.formatapplication/pdf-
dc.languageen-
dc.relationCSIR-CDRI Communication No. 8722-
dc.subjectAmino acids-
dc.subjectOxidative coupling-
dc.subjectVinyl sulfides-
dc.subjectWaste-free-
dc.titleAmino Acid and Water-Driven Tunable Green Protocol to Access S-S/C-S Bonds via Aerobic Oxidative Coupling and Hydrothiolation-
dc.typeArticle-
Appears in Collections:Medicinal and Process Chemistry

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